Family Service Units, a charity for children and families, went into administration this week following a significant decline in income and crippling pensions liabilities.
FSU, which has been operating since 1948 and runs services in England and Scotland, was a member of around a dozen local authority final salary pension schemes and faced a £5m pensions bill.
Chief executive Philippa Gitlin said this had "tipped [FSU] over the edge".
She said: "With a decline in income we did not see how we could make a surplus, generate enough to fund FSU services and pay off our pensions liabilities."
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